A study of charge quantization on ligand-stabilized Au5 cluster monolayers

Details A study of charge quantization on ligand-stabilized Au5 cluster monolayers A study of charge quantization on ligand-stabilized Au5 cluster monolayers

Apr 2003

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2003njph....5...30z&link_type=abstract

New Journal of Physics, Volume 5, Issue 1, pp. 30 (2003).

Physics

5

Scientific paper

Low-temperature ultrahigh-vacuum scanning tunnelling microscopy and spectroscopy was employed to analyse the electronic transport through the ligand-stabilized metal cluster Au55[P(C6H5)3]12Cl6, prepared as a monolayer on Au(111) substrates. The current-voltage behaviour is governed by charge-quantization phenomena expected for a nanometre-sized metallic particle. The related electric capacitances of the involved tunnelling junctions have been determined from accompanying current-distance measurements. Resonant tunnelling through states of the ligands can be ruled out as a relevant process in electronic transport through the clusters.

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