Physics – Atomic Physics
Scientific paper
2004-04-06
Physics
Atomic Physics
15 pages, 3 figures
Scientific paper
10.1063/1.1785782
We describe a modification of the inverted perturbation approach method allowing to construct physically sensible potential energy curves for electronic states of diatomic molecules even when some parts of the potential are not adequately characterized by the experimental data. The method is based on a simple regularization procedure, imposing an additional constraint on the constructed potential curve. In the present work it is applied to the double minimum 4$^1\Sigma^{+}_{\mathrm u}$ state of Na$_2$, observed experimentally by polarization labeling spectroscopy technique.
Grochola A.
Jastrzebski Wlodzimierz
Kowalczyk Piotr
Pashov Asen
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