A redetermination of the lifetime of the 4s 5s (3S1) level in Ca by high-rate electron-photon stepwise pulse excitation

Physics

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Atomic Excitations, Calcium, Continuous Wave Lasers, Oscillator Strengths, Photon-Electron Interaction, Radiative Lifetime, Atomic Beams, Laser Induced Fluorescence, Pulsed Lasers

Scientific paper

The radiative lifetime of the 4s 5s (3S1) level in Ca was measured during two-step excitation of atoms in a beam which traverses a cold-cathode Penning discharge, where, by electron impact, the atoms are excited to the metastable 4s 5p (3P2,1,0) states. Immediately thereafter, the beam is crossed with a pulse-modulated CW dye laser beam to populate the final state selectively. Using a pulse-modulation frequency of 0.5 MHz, a preliminary value of 12.4 + or - 0.5 ns was obtained with a statistical error of 0.4 percent. The wide limits of systematic error reflect an assumed uncertainty in the excitation function and possible distortion in the fluorescence decay requiring further study.

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