A re-evaluation of laser heterodyne radiometer ClO measurements

Physics

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Atmospheric Composition, Chlorine Oxides, Laser Spectroscopy, Molecular Spectra, Optical Heterodyning, Stratosphere, Atmospheric Chemistry, Balloon-Borne Instruments, Calibrating, Free Radicals, Infrared Absorption, Vertical Distribution

Scientific paper

Previously reported measurements of stratospheric ClO using a balloon-borne laser heterodyne radiometer, launched from Palestine, Texas, are re-evaluated as a result of recent spectroscopic data. A spectral feature which was observed during September, 1978 and November, 1979 flights was incorrectly identified as a ClO absorption line, while a second feature observed during the latter flight with somewhat limited sensitivity is now believed to be due to ClO. This new interpretation results in a measured ClO profile which falls off more rapidly with decreasing altitude than the previous results indicated.

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