A note on hydrogen isotope fractionation involving acidic and basic solutions

Details A note on hydrogen isotope fractionation involving acidic and basic solutions A note on hydrogen isotope fractionation involving acidic and basic solutions

Sep 1979

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1979gecoa..43.1575d&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 43, Issue 9, pp.1575-1577

Physics

Scientific paper

The dissociation constant of D 2 O is significantly lower than that of H 2 O, hence hydroxyl and hydronium ions have very much lower deuterium contents than the water from which they form. If the concentration of either of these ions becomes significant, its presence will effect the hydrogen isotope fractionation between any hydrogen bearing phase and the total solution.

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