A new triplet band system of C3 - The b 3Pi(g)-a 3Pi(u) transition

Details A new triplet band system of C3 - The b 3Pi(g)-a 3Pi(u) transition A new triplet band system of C3 - The b 3Pi(g)-a 3Pi(u) transition

Feb 1991

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1991jchph..94.2401s&link_type=abstract

Journal of Chemical Physics (ISSN 0021-9606), vol. 94, Feb. 15, 1991, p. 2401-2407. Research supported by the Petroleum Research

Physics

Chemical Physics

25

Carbon, Electron Transitions, Fine Structure, Molecular Spectra, Spectral Bands, Distributed Feedback Lasers, Laser Spectrometers, Semiconductor Lasers

Scientific paper

A triplet band system of C3 has been observed for the first time in absorption with a distributed-feedback (DFB) diode laser spectrometer and in emission with a Fourier transform spectrometer at around 6500/cm. The band has been assigned to the b 3Pi(g)-a 3Pi(u) system, and the spectroscopic constants in both the upper and lower states have been determined. It is demonstrated that near-infrared DFB lasers are promising radiation sources for spectroscopy of unstable molecules.

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