A new method for studying carbon clusters in the gas phase - Observations of size specific neutral fragment loss from metastable reactions of mass selected C(n)(+), n = 60 or less

Physics – Chemical Physics

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Carbon, Excimer Lasers, Heat Of Formation, Positive Ions, Vapor Phases, Comet Tails, High Pressure, High Resolution, Interstellar Space, Mass Spectrometers

Scientific paper

Carbon cluster ions are abundant in flames, interstellar space, and comet tails. In this paper, the fragmentation of metastable positive carbon cluster ions is reported. All C(n)(+) clusters with n = 5 or larger exhibit metastable reactions. The data are analyzed in terms of the possible structures of both the metastable ion and the neutral and ionic products.

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