A new chiral electro-optic effect: Sum-frequency generation from optically active liquids in the presence of a dc electric field

Physics – Optics

Scientific paper

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Submitted to Physical Review

Scientific paper

10.1103/PhysRevLett.91.173901

We report the observation of sum-frequency signals that depend linearly on an applied electrostatic field and that change sign with the handedness of an optically active solution. This recently predicted chiral electro-optic effect exists in the electric-dipole approximation. The static electric field gives rise to an electric-field-induced sum-frequency signal (an achiral third-order process) that interferes with the chirality-specific sum-frequency at second-order. The cross-terms linear in the electrostatic field constitute the effect and may be used to determine the absolute sign of second- and third-order nonlinear optical susceptibilities in isotropic media.

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