A laboratory measurement of the Doppler broadened N II line-width produced by electron impact excitation

Physics

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Doppler Effect, Electron Impact, Molecular Excitation, Nitrogen, Spectral Line Width, Atmospheric Radiation, Earth Atmosphere, Emission Spectra, Nitrogen Atoms, Upper Atmosphere

Scientific paper

It is found that the emission line-width of the N II (3p 3D-3d 3F0; 5005.15-A) line of ionized nitrogen is about 360 mA, when excited by 200-eV electron impact on N2. This result implies that an average ion fragment acquires a kinetic energy of about 8 eV in the dissociative excitation process and that about 8 percent of the energy of the incident 200-eV electron is converted directly into fragment kinetic energy. Such a large Doppler broadening would make it relatively easy for ground-based measurements to separate the relative contributions of direct excitation of atomic nitrogen and dissociative excitation of N2 to the source of this emission feature in the earth's upper atmosphere.

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