a Far Infrared Synchrotron-Based Investigation of 3-OXETANONE

Details a Far Infrared Synchrotron-Based Investigation of 3-OXETANONE a Far Infrared Synchrotron-Based Investigation of 3-OXETANONE

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..conferg13c&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Physics

Infrared/Raman

Scientific paper

The four membered ester ring 3-oxetanone is a precursor for adding oxetane subunits into pharmaceuticals which then block metabolically exposed sites in the bioactive molecule without increasing its lipophilicity. The high resolution (0.00096 cmCm-1) rovibrational spectrum of 3-oxetanone was recorded for the first time using far infrared radiation from the Canadian Light Source (CLS) synchrotron facility coupled to a Bruker IFS125HR FTIR spectrometer. A total of six rotationally-resolved vibrational bands were observed between 360 and 1150 cmCm-1 at room temperature. The assignment of the dense spectrum is currently underway and the progress will be discussed in this talk.

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