A Comparison of Adsorption and Boundary Lubricant Failure

Details A Comparison of Adsorption and Boundary Lubricant Failure A Comparison of Adsorption and Boundary Lubricant Failure

Feb 1974

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1974rspsa.336..407s&link_type=abstract

Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, Volume 336, Issue 1607, pp. 407-419

Physics

Scientific paper

A comparison has been made between the reversible adsorption and the friction-reducing properties of long-chain fatty amines on stainless steel. This has shown that adsorption and lubricant failure depend on concentration of amine and temperature in a similar way. Breakdown of lubrication may therefore be associated with reversible desorption of amines from steel surfaces. Measurement of the adsorption properties of the fatty amines indicates a lowering of the isosteric heat of adsorption at low temperatures, which may result from 'pre-freezing' of the hydrocarbon solvent.

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