Physics
Scientific paper
Apr 1999
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1999georl..26.1133m&link_type=abstract
Geophysical Research Letters, Volume 26, Issue 8, p. 1133-1136
Physics
14
Atmospheric Composition And Structure: Aerosols And Particles, Atmospheric Composition And Structure: Middle Atmosphere-Composition And Chemistry, Atmospheric Composition And Structure: Middle Atmosphere-Constituent Transport And Chemistry
Scientific paper
Each spring a layer of small particles forms between 20 and 30 km altitude in the polar regions. We present the first self-consistent explanation of the observed ``CN layer'' from a 2D microphysical model of sulfate aerosol. Our theory relies on photolysis of H2SO4 and SO3, consistent with recent laboratory measurements, to produce SO2 in the upper stratosphere and mesosphere. An additional source of SO2 may be required. Nucleation throughout the polar winter extends the top of the aerosol layer to higher altitudes, despite strong downward transport of ambient air. This may affect heterogeneous chemistry at the top of the aerosol layer in polar winter and spring.
Mills Michael J.
Solomon Susan
Toon Brian O.
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