16O13C18O: high-resolution absorption spectrum between 4000 and 9500cm-1 and global fitting of vibration-rotational line positions

Details 16O13C18O: high-resolution absorption spectrum between 4000 and 9500cm-1 and global fitting of vibration-rotational line positions 16O13C18O: high-resolution absorption spectrum between 4000 and 9500cm-1 and global fitting of vibration-rotational line positions

Dec 2003

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2003jmosp.222..276d&link_type=abstract

Journal of Molecular Spectroscopy, Volume 222, Issue 2, p. 276-283.

Physics

5

Scientific paper

The absorption spectrum of a 13C enriched carbon dioxide sample has been recorded with a Fourier-transform spectrometer in the spectral range 4000-9500cm-1. In addition to six bands observed from the spectrum of the atmosphere of Venus in this region, eight new 16O13C18O bands were measured. The new observations together with the data collected from the literature have been used to fit parameters of an effective Hamiltonian for the 16O13C18O. More than 4000 line positions in 38 bands have been used to derive 48 parameters of effective Hamiltonian. The RMS (root-mean-square of residuals) of the fit is 0.00106cm-1.

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