1-PHENYLPYRROLE - a Tict Molecule?.

Details 1-PHENYLPYRROLE - a Tict Molecule?. 1-PHENYLPYRROLE - a Tict Molecule?.

Jun 2009

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..confetb06t&link_type=abstract

"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec

Physics

Electronic

Scientific paper

1-Phenylpyrrole has been identified by several authors as a molecule that displays twisted intramolecular charge-transfer (TICT) character in the condensed phase. However, Suzuka and coworkers, using single vibronic level dispersed fluorescence, observed no evidence of TICT activity in the gas phase. In this work, 1-phenylpyrrole is studied by the high resolution methods previously applied to DMABN to determine the extent of its motion along different possible TICT coordinates when it absorbs light.
[2] K. Okuyama, Y. Numata, S. Odawara, and I. Suzuka, J. Chem. Phys., 109, 7185 (1998) and references therein.
[3] A. E. Nikolaev, G. Myszkiewwicz, G. Berden, L. Meerts, J. F. Pfanstiel, and D. W. Pratt, J. Chem. Phys., 122, 084309 (2005).

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