Carbonaceous Matter in the ISM

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Interstellar Dust Grains, Diffuse Emission, Infrared Cirrus, Molecular Clouds, H2 Clouds, Dense Clouds, And Dark Clouds, Molecular And Chemical Processes And Interactions, Chemical Composition And Chemical Evolution

Scientific paper

Observed infrared spectra of interstellar matter are compared to laboratory data and are used to constrain the composition of carbonaceous material (molecules and dust) in interstellar clouds. It is found that variations in the relative abundance of CH2 and CH3 groups indicate changes in chemical environment. In particular, a high abundance of CH3 groups is indicative of a dynamic chemistry. The connection between molecules and dust is explored and it appears that large interstellar molecules are probably created by the destruction of dust particles in the vicinity of energetic sources. Using new lab data on the IR spectrum of long chain n-alkanes, it is shown that there is little evidence for molecules of this type in the ISM. On the other hand, other laboratory and theoretical spectra suggest that dehydrogenated aromatic hydrocarbon molecules such as C24Hx (dehydrogenated coronene) are important interstellar species.

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