Nd and Sr isotope geochemistry of island arc volcanics, Grenada, Lesser Antilles

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Scientific paper

87Sr/86Sr and 143Nd/144Nd ratios, REE, K2O, Rb and Sr are presented for a variety of basanitoids, alkalic and subalkalic basalts, and calc-alkalic rocks from the island of Grenada, Lesser Antilles. The 87Sr/86Sr ratios vary from 0.7039 to 0.7058 whereas, with one exception, the 143Nd/144Nd ratios cover a small range from 0.51282 to 0.51308. There is a reasonable correlation between Sm/Nd and 143Nd/144Nd, but not between Rb/Sr and 87Sr/86Sr. The ankaramites tend to have higher K2O and Sr contents, but lower 87Sr/86Sr ratios than the microphyric basalts. A broad negative correlation between Nd and Sr isotopes is observed but it is both displaced to relatively higher 87Sr/86Sr ratios and has a flatter slope than most of the available results on mid-ocean ridge and ocean island basalts. The high 87Sr/86Sr ratios are thought to reflect a contribution from seawater affected material in the subducted ocean crust and yet they are observed in SiO2-undersaturated rocks which are most unlikely to have been derived by melting of subducted ocean crust. This is reconciled in a model whereby the alkalic elements are preferentially released during dehydration of the subducted lithosphere and contaminate the overlying mantle source region of the arc magmas.

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