Comparison of the soluble products from radiolysis and photolysis of CS2

Details Comparison of the soluble products from radiolysis and photolysis of CS2 Comparison of the soluble products from radiolysis and photolysis of CS2

May 2001

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2001rapc...61..115c&link_type=abstract

Radiation Physics and Chemistry, Volume 61, Issue 2, p. 115-121.

Physics

3

Scientific paper

Soluble products from the radiolysis of CS2 with gamma variable rays from 60Co, include elemental sulfur and CmSn compounds. These compounds were essentially the same as those that had already been reported for the UV photolysis of CS2. The amount of sulfur formed was proportional to the irradiation dose. The radiolysis also formed a dark colored, insoluble polymer in amounts proportional to the irradiation dose. The soluble CmSn molecules found in this work were most likely due to `aborted polymerization'. Radiolysis and photolysis of CS2 may contribute important C-S compounds for the cosmochemistry of circumstellar and interstellar media as well as of comets and atmospheres of the giant planets.

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