Light hydrocarbons from plasma discharge in H2-He-CH4 - First results and Uranian auroral chemistry

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Atmospheric Chemistry, Auroras, Hydrocarbons, Hydrogen, Methane, Planetary Composition, Plasma Jets, Uranus Atmosphere, Atmospheric Composition, Experiment Design, Miranda, Ultraviolet Spectroscopy, Voyager 2 Spacecraft

Scientific paper

The production of light hydrocarbons by precipitating magnetospheric electrons in the Uranian stratosphere is simulated in laboratory experiments. The products of continuous-flow glow discharges of H2-He-CH4 mixtures containing 0.0012 or 0.022 mol pct CH4 at pressures 0.63-57 mbar are trapped at 77 K, measured manometrically, and identified by gas chromatography and mass spectroscopy; the results are presented in tables and characterized in detail. The globally averaged rate for the production of higher hydrocarbons by this mechanism on Uranus is estimated as 3 x 10 to the 6th C/sq cm sec and shown to be similar to that for photochemical production, while the local rate for the auroral zones is significantly higher than the corresponding photochemical rate. A decrease in yield with increasing molecular complexity is also noted.

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