The Law of Conservation of Energy in Chemical Reactions

Details The Law of Conservation of Energy in Chemical Reactions The Law of Conservation of Energy in Chemical Reactions

2000-10-21

arxiv.org/abs/physics/0010052v1

Physics

Chemical Physics

e-mail me istepanov@email.com, 10 pages

Scientific paper

Earlier it has been supposed that the law of conservation of energy in chemical reactions has the following form: DU=DQ-PDV+SUM(muiDN) In the present paper it has been proved by means of the theory of ordinary differential equations that in the biggest part of the chemical reactions it must have the following form: DU=DQ+PDV+SUM(muiDN) The result obtained allows to explain a paradox in chemical thermodynamics: the heat of chemical processes measured by calorimetry and by the Vant-Hoff equation differs very much from each other. The result is confirmed by many experiments.

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