Non-LTE radiative transfer in the 4.7 and 2.3 μm bands of CO: vibration-rotational non-LTE and its effects on limb radiance.

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Radiative Transfer: Earth Atmosphere, Radiative Transfer: Carbon Monoxide

Scientific paper

Vibrational temperatures and rotational distributions for the two lowest vibrational levels of CO molecules are calculated for day and night conditions for the altitude region between 0 and 150 km. The effects of vibrational and rotational non-LTE on the limb radiance distribution in the 4.7 μm fundamental and hot bands as well as in the 2.3 μm first overtone band are analyzed and implications for remote sensing with high spectral resolution instruments are discussed.

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