The vibration-rotation emission spectrum of CH(X 2Pi)

Details The vibration-rotation emission spectrum of CH(X 2Pi) The vibration-rotation emission spectrum of CH(X 2Pi)

May 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987jchph..86.4838b&link_type=abstract

Journal of Chemical Physics (ISSN 0021-9606), vol. 86, May 1, 1987, p. 4838-4842. Research supported by the Petroleum Research F

Physics

Chemical Physics

51

Emission Spectra, Free Radicals, Methane, Rotational Spectra, Rydberg Series, Vibrational Spectra, Carbon Stars, Fourier Transformation, Ground State, Inert Atmosphere, Magnetic Resonance, Solar Atmosphere, Ultraviolet Spectra

Scientific paper

Fourier transform spectrometer observations of the vibration-rotation emission spectrum of CH have led to the detection of the 1-0, 2-1, and 3-2 bands in a microwave discharge of allene in Ar and methane in He. A simultaneous fit of all line positions has yielded spectroscopic constants for v = 0, 1, 2, and 3, together with equilibrium molecular constants and an RKR potential curve. The RKR points were used as inputs to a centrifugal distortion program.

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