Universal functions for estimating total vibration-rotation band absorptance. III - Asymmetric tops

Physics

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Absorptance, Molecular Rotation, Spectral Bands, Vibrational Spectra, Ozone, Planetary Atmospheres, Radiative Transfer, Water

Scientific paper

A previous method of universal functions (MUF) for estimating total band absorptances and their derivatives for nonoverlapping lines of vibration-rotation bands of linear molecules and spherical and symmetric tops, is extended to asymmetric top bands. The universal functions for symmetric tops are employed. The accuracy of MUF is within a few percent for the 010-000 and 001-000 bands of H2O and O3 and Lorentz line shapes at temperatures of 175-325 K. A simple technique for obtaining an effective Lorentz width for all of the band lines is proposed for application to MUF.

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