Impact of new laboratory infrared spectroscopic results on ozone retrievals in the atmosphere

Physics

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Atmospheric Composition, Infrared Spectroscopy, Line Spectra, Ozonometry, Atmospheric Physics, Balloon-Borne Instruments, Isomers, Oxygen Isotopes, Remote Sensing, Spectral Line Width

Scientific paper

A comprehensive compilation of improved line positions, intensities, and lower state energies has been generated for ozone between 0 and 3400/cm by combining the best experimental results with powerful theoretical methods. Various examples are presented which clearly show the improvements obtained with these new results compared to previously available line parameters. The importance of hot band absorption in atmospheric spectra is also demonstrated. It is shown that, without these new results, the first detection and measurement of the isotopic species (O-16)(O-16)(O-18) and (O-16)(O-18)(O-16) in the atmosphere by balloon-borne interferometer would not have been possible.

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