Solar irradiance in the stratosphere - Implications for the Herzberg continuum absorption of O2

Physics

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Absorption Cross Sections, Atmospheric Attenuation, Herzberg Bands, Oxygen, Solar Flux Density, Stratosphere, Balloon-Borne Instruments, Ozone, Solar Spectra, Ultraviolet Radiation

Scientific paper

A set of solar irradiance observations is analyzed that were performed from the third Solar Absorption Balloon Experiment (SABE-3) as the payload ascended through the stratosphere from 32 to 39 km. Comparison of these data with calculations of the attenuated irradiance based on simultaneous ozone and pressure measurements made from the payload suggests a refinement of the cross section values used in photochemical models. More ultraviolet radiation in the 200-210 nm spectral region reaches the middle stratosphere than is predicted by the absorption data presently available. It is suggested that significantly smaller values for the Herzberg continuum of O2 be used in future models.

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