An observation of CH/+/ following a high altitude release of trimethylaluminium

Details An observation of CH/+/ following a high altitude release of trimethylaluminium An observation of CH/+/ following a high altitude release of trimethylaluminium

Feb 1979

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1979jatp...41..169b&link_type=abstract

Journal of Atmospheric and Terrestrial Physics, vol. 41, Feb. 1979, p. 169-171, 173-177.

Physics

Artificial Clouds, Atmospheric Chemistry, Methyl Compounds, Molecular Ions, Organic Aluminum Compounds, Cations, Spectrum Analysis

Scientific paper

An unexpected feature in the spectrum of a twilight release of trimethylaluminium at 160 km altitude is identified as being due to CH(+) formed following the release. All other spectroscopic possibilities are eliminated. Its formation at the rate observed can not be explained by any known sequence of exothermic reactions. It also disappears in several seconds but this can be accounted for by dissociative recombination or by reactions with ambient atomic oxygen. The maximum yield of ions is estimated to be about 4% of the AlO yield.

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