The one electron reduction of Hg2+ by 1-hydroxyalkyl radicals in aqueous solution: a pulse radiolysis study

Physics

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Divalent Mercury Ion, 1-Hydroxyalkyl Radicals, One Electron Reduction, Rate Constant, Pulse Radiolysis

Scientific paper

The rate constants for the reduction of the divalent mercury ion Hg2+ by alcohol radicals, which are produced in acidic aqueous solutions containing methanol, ethanol or 2-propanol, are determined by optical absorption measurements to be 7.0×108, 3.8×108 or 3.1×108dm3mol-1s-1, respectively.

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