Thermal Synthesis of Nucleoside H-Phosphonates Under Mild Conditions

Details Thermal Synthesis of Nucleoside H-Phosphonates Under Mild Conditions Thermal Synthesis of Nucleoside H-Phosphonates Under Mild Conditions

Feb 2005

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2005oleb...35....1d&link_type=abstract

Origins of Life and Evolution of Biospheres, Volume 35, Issue 1, pp.1-10

Physics

4

Nucleotides, Phosphite, Phosphodiester Synthesis, Nucleoside Phosphite, Prebiotic Phosphorylation

Scientific paper

Nucleosides react rapidly with ammonium phosphite ((NH4)2HPO3) at 60 °C to produce good yields of nucleoside-5’-phosphite monoesters within 24 h. Under the same conditions, ammonium phosphate is unreactive, producing low yields of nucleotide only after extended reactions. These results confirm earlier suggestions that nucleoside H-phosphonates and their possible condensation products may have been produced on the primitive earth more easily than nucleotides.

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