Stark broadening and regularities of prominent spectral lines of multiply ionized chlorine and fluorine

Physics – General Physics

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Chlorine, Fluorine, Gas Ionization, Plasma Spectra, Spectral Line Width, Stark Effect, Ionization Potentials, Optical Transition, Plasma Diagnostics

Scientific paper

Stark widths of six Cl II, eight Cl III, three Cl IV, and two F III spectral lines and Stark shifts of six Cl II and eight Cl III spectral lines have been measured in a linear-pinch discharge plasma and compared with available experimental and theoretical data. The electron density determined by single-wavelength laser interferometry using the visible 632.8-nm transition of a He-Ne laser was 1.97 x 10 to the 23rd/cu m. An electron temperature of 27,000 K was determined. Since the majority of Cl II, Cl III, and Cl IV spectral lines investigated originate from 4s-4p transition arrays, the Stark-width dependence on the upper-level ionization potential of corresponding lines is established and discussed both within one stage of ionization of chlorine and within several stages of ionization of chlorine and fluorine. The Stark-width dependence on the net charge of the emitter core acting upon the optical electron undergoing transition is found.

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