Kinetic parameters related to sources and sinks of vibrationally excited OH in the nightglow

Details Kinetic parameters related to sources and sinks of vibrationally excited OH in the nightglow Kinetic parameters related to sources and sinks of vibrationally excited OH in the nightglow

Jul 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987jgr....92.7643m&link_type=abstract

Journal of Geophysical Research (ISSN 0148-0227), vol. 92, July 1, 1987, p. 7643-7650.

Physics

46

Atmospheric Models, Hydroxyl Radicals, Ion Concentration, Nightglow, Vibrational Spectra, Mesosphere, Quantum Theory, Radiative Transfer

Scientific paper

Kinetic parameters related to vibrational deactivation and chemical removal of vibrationally excited OH radical in the mesosphere are deduced from ground-based measurements of the mean vibrational distributions of the OH Meinel bands in the nightglow. It is shown that the OH Meinel band emission can be adequately explained with the deduced parameters and the H + O3 - OH + O2 reaction as the only chemical source of vibrationally excited OH. Evidence is presented which suggests that the reversible reaction HO2 + O - HO + O2 may be involved as a sink of vibrationally excited OH rather than as a potential source.

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