Physics
Scientific paper
Nov 2008
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2008georl..3522101c&link_type=abstract
Geophysical Research Letters, Volume 35, Issue 22, CiteID L22101
Physics
35
Planetary Sciences: Solar System Objects: Mars, Geochemistry: Geochemical Modeling (3610, 8410), Geochemistry: Thermodynamics (0766, 3611, 8411), Global Change: Geomorphology And Weathering (0790, 1824, 1825, 1826, 1886)
Scientific paper
We have studied the low-temperature properties of ferric sulfate Fe2(SO4)3 solutions as a model for potential liquid brines on the surface of Mars. Geochemical modeling demonstrates that concentrated ferric sulfate brines form through sulphur-rich acidic evaporation processes in cold oxidizing environments. Experiments and thermodynamic calculations show that the Fe2(SO4)3 eutectic temperature is 205 +/- 1 K for 48 +/- 2 wt% concentration. As a result of low water activity, these solutions exhibit evaporation rates ranging from 0.42 mm h-1 (29.1 wt%) to 0.03 mm h-1 (58.2 wt%), thus down to 20 times lower than pure water. The combination of extremely low eutectic temperature and evaporation rates allow subsurface liquids to be stable at high latitudes, where the majority of gullies and viscous flow features are located. Therefore, we conclude that episodic releases of highly concentrated ferric sulfate brines are a potential agent for the formation of recent and present-day gullies on Mars.
Altheide Travis S.
Chevrier Vincent F.
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