Lambda doubling in the infrared spectrum of SH

Physics

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Astronomical Spectroscopy, Hydrides, Infrared Spectra, Molecular Spectroscopy, Sulfur Compounds, Molecular Rotation, Spectral Bands, Spectrum Analysis

Scientific paper

The (1-0), (2-1), and (3-2) IR vibrational-rotational bands of the X2Pi ground state of gaseous SH are investigated experimentally using the 1-m Fourier-transform spectrometer at Kitt Peak National Solar Observatory. The results are presented in tables and spectra and characterized. A total of 285 lines are measured for the three bands; R-branches and heads are observed; and the clearly resolved lambda splitting of rotational lines for each component of the multiplet is used to calculate lambda-doubling parameters for each band.

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