Physics – Atomic Physics
Scientific paper
2004-05-14
Lithuanian Journal of Physics 40 (2000) 395-405
Physics
Atomic Physics
Scientific paper
The general tensorial form of the orbit-orbit interaction operator in the formalism of second quantization is presented. Such an expression is needed to calculate both diagonal and off-diagonal matrix elements with respect to configurations, in a uniform way. Some special cases are shown for which the orbit-orbit interaction operator reduces to simple form. The importance of different contributions to the Breit-Pauli hamiltonian is investigated in ground states and ionization potentials for Li isoelectronic sequency in the systematic way.
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