Physics – Chemical Physics
Scientific paper
2010-04-05
Phys. Chem. Chem. Phys., v.12 2010, 13273 - 13279
Physics
Chemical Physics
7 pages, 3 figures
Scientific paper
This paper is devoted to the multiple-quantum (MQ) NMR spectroscopy in nanopores filled by a gas of spin-carrying molecules (s=1/2) in a strong external magnetic field. It turned out that the high symmetry of the spin system in nanopores yields a possibility to overcome the problem of the exponential growth of the Hilbert space dimension with an increase in the number of spins and to investigate MQ NMR dynamics in systems consisting of several hundred spins. We investigate the dependence of the MQ coherence intensities on their order (the profile of the MQ coherence intensities) for a spin system governed by the standard MQ NMR Hamiltonian (the nonsecular two-quantum/two-spin Hamiltonian) together with the second order correction of the average Hamiltonian theory. It is shown that the profile depends on the value of this correction and varies from the exponential to the logarithmic one.
Doronin Sergei I.
Fedorova Anna V.
Fel'dman Edward B.
Zenchuk Alexander I.
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