Physics – Chemical Physics
Scientific paper
2008-04-30
Int. J. Mass. Spectrom. 280, 19 (2009)
Physics
Chemical Physics
19 pages, 7 figures, submitted to Int. J. Mass Spec
Scientific paper
10.1016/j.ijms.2008.06.010
We examine the effects of a linearly polarized nonresonant radiative field on the dynamics of rotationally inelastic $\text{Na}^{+} + \text{N}_2$ collisions at eV collision energies. Our treatment is based on the Fraunhofer model of matter wave scattering and its recent extension to collisions in electric fields [arXiv:0804.3318v1]. The nonresonant radiative field changes the effective shape of the target molecule by aligning it in the space-fixed frame. This markedly alters the differential and integral scattering cross sections. As the cross sections can be evaluated for a polarization of the radiative field collinear or perpendicular to the relative velocity vector, the model also offers predictions about steric asymmetry of the collisions.
Friedrich Bretislav
Lemeshko Mikhail
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