Physics – Plasma Physics
Scientific paper
2008-03-10
International Journal of Mass Spectrometry 277 (2008) 220-222
Physics
Plasma Physics
7 pages, 6 figures, submitted to International Journal of Mass Spectrometry, issue in honor of E. Illenberger
Scientific paper
10.1016/j.ijms.2008.05.013
A new analysis and new Molecular Dynamics (MD) simulations of the measurements of the mobility $\mu_{i}$ of O$_{2}^{-} $ ions in dense supercritical Ar gas are reported. $\mu_{i}$ shows a marked dependence on the distance from the critical temperature $T_{c}.$ A mobility defect appears as a function of the gas density and its maximum value occurs below the critical density. The locus of points of maximum mobility defect in the $P-T$ plane appears on the extrapolation of the coexistence curve into the single-phase region. MD simulations quantitatively reproduce the mobility defect near $T_{c}.$
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