Levy-Lieb constrained-search formulation as a minimization of the correlation functional

Details Levy-Lieb constrained-search formulation as a minimization of the correlation functional Levy-Lieb constrained-search formulation as a minimization of the correlation functional

2007-04-03

arxiv.org/abs/0704.0372v1

Journal of Physics A:Math.Theor.40, 2787 (2007)

Physics

Quantum Physics

9 pages, no figures

Scientific paper

The constrained-search formulation of Levy and Lieb, which formally defines the exact Hohenberg-Kohn functional for any N-representable electron density, is here shown to be equivalent to the minimization of the correlation functional with respect to the N-1 conditional probability density, where N is number of electrons of the system. The consequences and implications of such a result are here analyzed and discussed via a practical example.

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