Ion Composition of Comet 19P/Borrelly as Measured by the PEPE Ion Mass Spectrometer on DS1

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6005 Atmospheres: Composition And Chemistry, 6006 Atmospheres: Evolution, 6008 Composition, 6040 Origin And Evolution, 6045 Physics And Chemistry Of Materials

Scientific paper

Cometary compositions are of great interest because they hold important clues to the formation of the outer solar system, and to the sources of volatiles in the solar system, including the terrestrial planets. In order to understand the primordial compositions of cometary nuclei, it is important to also understand their evolution, as many of the comets most accessible to spacecraft are highly evolved. It is also important to understand the ion and neutral chemistry that occurs in the coma surrounding the nucleus if the coma ion composition is to be used to determine the original composition of the nucleus. Deep Space One (DS1) was only the second spacecraft, after Giotto, to use an ion mass-resolving instrument to explore cometary coma compositions in-situ, which it did during the flyby of Comet Borrelly on September 22, 2001. Borrelly is significantly more evolved than Halley. In addition, the encounter occurred at a significantly greater distance from the sun (1.36 AU vs 0.9 AU for Giotto at Halley). The Plasma Experiment for Planetary Exploration (PEPE) on board DS1 was capable of resolving electron and ion energy, angle of incidence, and ion mass composition. The PEPE ion data from the seven minutes surrounding closest approach (2171 km) have been extensively analyzed. The instrument response was modeled using SIMION and TRIM codes for all of the major species through 20 AMU plus CO (at its operating voltage PEPE was very insensitive to heavier molecules). Chi-squared minimization analysis is being carried out to determine the best fit and the uncertainties. Preliminary results for the predominant heavy ions are OH+ at (72 +/- 9)% of the total water-group ion density, H2O+ at (25 +/- 7)%, CH3+ at (5 +/- 3)%, and O+ at (4 +/- 5)%. Uncertainties are quoted at the 90% confidence level. Comparison with reported Halley compositions from Giotto shows that Borrelly clearly has a lower H3O+ abundance (< 9%), consistent with a more evolved comet. The presence of relatively high amounts of CH3+, proposed in the context of Halley to be produced by protonation of CH2+, is somewhat surprising in this context. Because the H3O+/H2O+ ratio is an indicator of the degree of protonation in the coma, a low H3O+/H2O+ ratio would predict a low CH3+/CH2+ ratio as well. However, this is not the case at Borrelly. The CH3+/H3O+ ratio will need further study in future comet models and observations.

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