Possibility of /Mg-24/H/+/ in the solar atmosphere - High resolution rotation-vibration spectra

Physics

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High Resolution, Rotational Spectra, Solar Atmosphere, Solar Spectra, Vibrational Spectra, Absorption Spectra, Magnesium Compounds, Spectral Bands, Tables (Data), Transition Probabilities

Scientific paper

High-resolution spectra of the fundamental and first-overtone sequences of (Mg-24)H(+) vibration-rotation bands are reported which were obtained by a differencing process invoking the known structures of electronic bands in the spectral region from 214 to 340 nm. The J = 1 - J = 0 millimeter-wave emission in each of the first four lowest vibrational levels of the 1 Sigma(+) ground electronic state is predicted to occur at 376.098, 365.301, 354.286, and 342.981 GHz, respectively. Rotational constants and equilibrium rotational constants are derived for the X1 Sigma(+) state of (Mg-24)H(+). It is noted that the R branch reverses for sufficiently high J, resulting in band-head formation for the pertinent vibration-rotation band.

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