The photochemical time constants of minor constituents and their families in the middle atmosphere

Details The photochemical time constants of minor constituents and their families in the middle atmosphere The photochemical time constants of minor constituents and their families in the middle atmosphere

Feb 1984

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1984jatp...46..173s&link_type=abstract

Journal of Atmospheric and Terrestrial Physics (ISSN 0021-9169), vol. 46, Feb. 1984, p. 173-191.

Physics

18

Atmospheric Chemistry, Middle Atmosphere, Photochemical Reactions, Constants, Photolysis, Reaction Kinetics, Tables (Data), Vertical Distribution

Scientific paper

A comprehensive formula is worked out for the photochemical time constant of minor constituents in the middle atmosphere. The formula is particularly useful for evaluating the time constants for families of some chemical species that are strongly coupled by rapid exchange reactions. Height profiles of photochemical time constants are calculated for individual species and their families based on the chemical reaction rate constants recommended in the recent WMO and JPL reports. Potential exchange reactions among various family members are discussed, and the effects of the choice of family membership on the time constant are evaluated.

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