Line strengths of N2O in the 1120-1440/cm region

Physics – Optics

Scientific paper

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Atmospheric Optics, Infrared Absorption, Nitrous Oxides, Oscillator Strengths, Spectrum Analysis, Vibrational Spectra, Carbon Dioxide, Electric Moments, Forbidden Bands, Isotopes, Perturbation Theory, Solar Spectra, Spectral Bands

Scientific paper

Line strengths of N2O and its isotopic derivatives in the 1120-1440/cm region were measured at low pressure and high resolution (0.0054/cm). The band strength, rotationless dipole moment matrix elements, and F factor coefficients were considered. First-order nondegenerate perturbation theory was employed to derive explicit expressions for the rotationless dipole moment matrix elements and F factor coefficients. This made it possible to obtain general expressions for the F factor. The derived expressions were also applicable to CO2 bands.

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