Multi-configuration Hartree-Fock plus Breit-Pauli results for some forbidden transitions

Astronomy and Astrophysics – Astrophysics

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Configuration Interaction, Forbidden Transitions, Hartree Approximation, Relativistic Effects, Transition Probabilities, Wave Functions, Astrophysics, Fine Structure, Nickel, Plasma Diagnostics, Sulfur, Tokamak Devices

Scientific paper

The multiconfiguration Hartree-Fock method, extended to include relativistic effects in the Breit-Pauli approximation (MCHF + BP), has been applied to the study of some forbidden transitions between levels of the 3s(2)3p(3) configuration in the phosphorus sequence. Term energy separations, fine-structure splittings, and E2 and M1 transition rates are reported for S II, of interest in astrophysics, and for several atomic systems with nuclear charge, Z, in the range Z = 28-42, where lines have been observed in laboratory plasmas. The results are compared with values derived from observation and with other theories.

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