Relativistic corrections of mα^6(m/M) order to the hyperfine structure of the H_2^+ molecular ion

Physics – Atomic Physics

Scientific paper

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13 pages, 2 figures, 4 tables

Scientific paper

10.1103/PhysRevA.79.012501

The m\alpha^6(m/M) order corrections to the hyperfine splitting in the H_2^+
ion are calculated. That allows to reduce uncertainty in the frequency
intervals between hyperfine sublevels of a given rovibrational state to about
10 ppm. Results are in good agreement with the high precision experiment
carried out by Jefferts in 1969.

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