Charge transfer between nitrogen cations and nitrogen at low energies

Physics – Plasma Physics

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Scientific paper

The measurement of charge transfer rate coefficients between multiply charged ions and neutral atoms and molecules is important in the areas of plasma physics and astro-physics. Such a measurement is also essential in verifying various theoretical electron capture processes. N 2+ is of particular interest since it is abundant in astrophysical nebulas and interstellar molecular clouds. The charge transfer rate coefficient for the charge exchange reaction between N 2+ [2 s 2 2 p ( 2 P 0 )] and N 2 is measured using ion trap techniques. N 2+ ions are produced by electron impact ionization of N 2 and stored inside a cylindrical rf trap. The charge transfer rate coefficient is determined by measuring the decay rate of stored N 2+ ions in the ion trap. The measured charge transfer rate coefficient between N 2+ and N 2 is 1.95 ± 0.27 × 10^-9 cm 3 s -1 at T equiv = 9.1 × 10^3 K. The estimated uncertainty of ± 14% is mainly due to the statistical fluctuations of the ion signal and the N 2 particle density measurements. The charge transfer rate coefficient is within one standard deviation of previously published results.

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