Chemistry of middle atmospheric ionization - A review

Physics

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Atmospheric Chemistry, Atmospheric Ionization, Atmospheric Physics, Middle Atmosphere, Atmospheric Composition, Atmospheric Models, D Region, Mesosphere, Oxygen Atoms, Stratosphere, Troposphere

Scientific paper

Observations of the ionization chemistry of the middle atmosphere, defined as the region between 100 km and the tropopause and therefore comprising the stratosphere and D-region (50-100 km), are described. It is reported that: (1) new measurements of intermediate ion species in the D-region with rocket-borne mass spectrometers have allowed identification of dominant clustering paths; (2) the relative roles played by nitric oxide, atomic oxygen, and the neutral and electron temperatures have been identified for the D-region; and (3) ionic schemes, either specifically for the stratosphere or in the form of extensions of D-region schemes to stratospheric heights through the addition of extra reactions (including those involving aerosols), have been introduced.

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