Rate coefficient upper limits for the BrONO2 and ClONO2+O3 reactions

Details Rate coefficient upper limits for the BrONO2 and ClONO2+O3 reactions Rate coefficient upper limits for the BrONO2 and ClONO2+O3 reactions

Oct 1998

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1998georl..25.3567b&link_type=abstract

Geophysical Research Letters, Volume 25, Issue 19, p. 3567-3570

Physics

1

Atmospheric Composition And Structure: Chemical Kinetic And Photochemical Properties, Atmospheric Composition And Structure: Middle Atmosphere-Composition And Chemistry

Scientific paper

The gas phase reactions BrONO2 and ClONO2+O3->Products (k1 and k3) were examined at 235+/-2K and 700 Torr N2 using a Fourier transform infrared spectrometer coupled to a temperature regulated long path absorption cell. The loss of BrONO2 and ClONO2 were measured to be independent of the O3 concentration yielding k1<1×10-20cm3molecule-1s-1 and k3<4×10-21cm3molecule-1s-1.

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