Measurements of Lorentz-broadening coefficients and pressure-induced line shift coefficients in the nu2 band of D2(O-16)

Physics

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Heavy Water, Line Spectra, Pressure Broadening, Spectral Bands, Spectral Line Width, Spectral Resolution, Air, Least Squares Method, Nitrogen, Oxygen, Water Vapor

Scientific paper

Lorentz-broadening and pressure-induced line-shift coefficients are determined experimentally for 126 transitions in the nu2 band of D2(O-16) from laboratory spectra with a Fourier-transform spectrometer. A nonlinear least-squares fitting procedure is employed to measure transitions up to J double-prime = 12 in the buffer gases air, nitrogen, and oxygen. The N2-broadening/O2-broadening coefficient ratio is correlated with the magnitude of the O2-broadening coefficient, and the pressure coefficients are not correlated with line widths.

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