Physics
Scientific paper
Aug 1988
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1988georl..15..847t&link_type=abstract
Geophysical Research Letters (ISSN 0094-8276), vol. 15, Aug. 1988, p. 847-850.
Physics
92
Atmospheric Chemistry, Chlorine Compounds, Nitrates, Nitric Acid, Stratosphere, Sulfuric Acid, Hydrogen Chlorides, Mass Spectroscopy, Polar Regions
Scientific paper
The heterogeneous interactions of ClONO2, HCl, and HNO3 with sulfuric acid surfaces were studied using a Knudsen cell flow reactor. The surfaces studied, chosen to simulate global stratospheric particulate, were composed of 65-75 percent H2SO4 solutions at temperatures in the range -63 to -43 C. Heterogeneous loss, but not reaction, of HNO3 and HCl occurred on these surfaces; the measured sticking coefficients are reported. Chlorine nitrate reacted on the cold sulfuric acid surfaces, producing gas-phase HOCl and condensed HNO3. CLONO2 also reacted with HCl dissolved in the 65-percent H2SO4 solution at -63 C, forming gaseous Cl2. In all cases studied, the sticking and/or reaction coefficients were much larger for the 65-percent H2SO4 solution at -63 C than for the 75-percent solution at -43 C.
Golden David M.
Rossi Michel J.
Tolbert Margaret A.
No associations
LandOfFree
Heterogeneous interactions of chlorine nitrate, hydrogen chloride, and nitric acid with sulfuric acid surfaces at stratospheric temperatures does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Heterogeneous interactions of chlorine nitrate, hydrogen chloride, and nitric acid with sulfuric acid surfaces at stratospheric temperatures, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Heterogeneous interactions of chlorine nitrate, hydrogen chloride, and nitric acid with sulfuric acid surfaces at stratospheric temperatures will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-1694358