Continuous ultraviolet absorption by Si+ (4Pe): an exploratory R-matrix calculation.

Physics

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Laboratory Spectra:Silicon, Uv Absorption:Silicon

Scientific paper

The R-matrix method is used to calculate photoionization from the first excited state 3s3p2 3Pe of Si+. The lowest two triplet terms 3s3p 3P0 and 3p2 3Pe of the residual ion Si++ are included in the calculation. They are approximated by configuration interaction wavefunctions which are constructed from six spectroscopic orbitals: 1s, 2s, 2p, 3s, 3p, 3d. Partial and total cross-sections are tabulated for photon energies ranging from threshold (705 A) up to 2.5 Ryd (365 A). Some of the 3p2np autoionizing resonances are delineated and shown graphically.

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