Physics
Scientific paper
May 1985
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1985gecoa..49.1277g&link_type=abstract
Geochimica et Cosmochimica Acta, vol. 49, Issue 5, pp.1277-1279
Physics
Scientific paper
Solubility of Ti 4+ in ureyite (cosmochlor, NaCrSi 2 O 6 ) was experimentally studied at 1 atmosphere and 1000°C, using sodium disilicate as flux. Microprobe analyses indicate that at low titanium concentrations the substitution of titanium in ureyite is almost exclusively in the M1 site, coupled with a vacancy in the M2 site. At higher TiO 2 contents, a small additional amount enters the tetrahedral site. If the solubility of titanium is similar in jadeite and acmite, the TiSi 2 O 6 substitution could contribute significantly to the vacancy content of natural titanium bearing omphacites.
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