Physics
Scientific paper
Dec 2011
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011georl..3824306m&link_type=abstract
Geophysical Research Letters, Volume 38, Issue 24, CiteID L24306
Physics
Mineral Physics: Elasticity And Anelasticity, Mineral Physics: High-Pressure Behavior, Mineral Physics: Physical Thermodynamics, Mineral Physics: X-Ray, Neutron, And Electron Spectroscopy And Diffraction
Scientific paper
We measured the phonon density of states (DOS) of hexagonal close-packed iron ($\varepsilon$-Fe) with high statistical quality using nuclear resonant inelastic X-ray scattering and in situ X-ray diffraction experiments between pressures of 30 GPa and 171 GPa and at 300 K, with a neon pressure medium up to 69 GPa. The shape of the phonon DOS remained similar at all compression points, while the maximum (cutoff) energy increased regularly with decreasing volume. As a result, we present a generalized scaling law to describe the volume dependence of $\varepsilon$-Fe's total phonon DOS which, in turn, is directly related to the ambient temperature vibrational Grüneisen parameter (γvib). Fitting our individual γvib data points with γvib = γvib,0(V/V0)q, a common parameterization, we found an ambient pressure γvib,0 = 2.0 ± 0.1 for the range q = 0.8 to 1.2. We also determined the Debye sound velocity (vD) from the low-energy region of the phonon DOS and our in situ measured volumes, and used the volume dependence of vD to determine the commonly discussed Debye Grüneisen parameter (γD). Comparing our γvib(V) and γD(V), we found γvib to be ∼10% larger than γD at any given volume. Finally, applying our γvib(V) to a Mie-Grüneisen type relationship and an approximate form of the empirical Lindemann melting criterion, we predict the vibrational thermal pressure and estimate the high-pressure melting behavior of $\varepsilon$-Fe at Earth's core pressures.
Chen Bin
Jackson Jennifer M.
Murphy Caitlin A.
Sturhahn Wolfgang
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